Investigating Challenges of Using Ammonia as a Future Fuel for Marine Industry: A Review

Erkan Oterkus

University of Strathclyde

Kishore Bedekar

Unversity of Strathclyde

Selda Oterkus

University of Strathclyde

DOI: https://doi.org/10.36956/sms.v6i2.1155

Received: 8 July 2024 | Revised: 18 August 2024 | Accepted: 16 September 2024 | Published Online: 25 September 2024

Copyright © 2024 Erkan Oterkus, Kishore Bedekar, Selda Oterkus. Published by Nan Yang Academy of Sciences Pte. Ltd.

Creative Commons LicenseThis is an open access article under the Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC 4.0) License.


Abstract

To reduce the greenhouse gases as per the forthcoming IMO rules, ammonia seems to be a suitable fuel for marine industry since it’s a hydrogen carrier and a carbon, Sulphur, and particulate matter free fuel. It has high volumetric hydrogen density, low storage pressure, and high auto ignition temperature. Ammonia can be used directly in internal combustion engines, and gas turbines.  Cracked hydrogen can be used for fuel cells. The 4th IMO Greenhouse Gas Study 2020, estimates that if no further action is taken, international shipping emissions are expected to represent 90% to 130% of 2008 emission levels by 2050. There will also be a rise in atmospheric CO2 and there is already a rise in average global sea levels from 21.9 to 23.7 between 1880 and 2010. This will affect large coastal areas of the world and island nations. The challenges for ammonia are its foul odor, corrosive nature, and being highly toxic to humans and the environment. There is also an explosion risk. Other issues are bunkering and storage on board, corrosive effect on metals, shore infrastructure, commercial and technical viability. Therefore, this study gives an overview of challenges that will be faced on board ships to use ammonia as fuel.

Keywords: Ammonia; GHG; IMO regulations; storage; CO2 free; toxic; corrosive; combustion properties


References

[1] Faber, J. et al. (2021), Fourth IMO GHG Study 2020, International Maritime Organization (IMO).

[2] Estela Morante, Article No. 99 [UNCTAD Transport and Trade Facilitation Newsletter N°96 - Fourth Quarter 2022] – 19th Dec. 2022

[3] IMO Resolution MEPC.377(80)

[4] Prevention of Air Pollution from Ships’, International Maritime Organization, UK:http://www.imo.org/en/OurWork/Environment/PollutionPrevention/AirPollution/Pages/Air-Pollution.aspx [Google Scholar]

[5] Sulphur Oxides (SOx) and Particulate Matter (PM) – Regulation 14’, IMO, UK:http://www.imo.org/en/OurWork/Environment/PollutionPrevention/AirPollution/Pages/Sulphur-oxides-(SOx)-%E2%80%93-Regulation-14.aspx[Google Scholar]

[6] PNAS - Political leadership has limited impact on fossil fuel taxes and subsidies https://doi.org/10.1073/pnas.2208024119 - November 14, 2022, Cesar B. Martinez-Alvarez, Chad Hazlett, Pasha Mahdavi, and Michael L. Ross

[7] Limitations of Ammonia as a Hydrogen carrier for the transport sector – ACS Energy letter- 2021, 6, 4390-4394 S. Chatterjee, R.K. Parsapur, Kuo-Wei Huang

[8] The International Transport Forum (ITF). Decarbonising Maritime Transport Pathways to Zero-Carbon Shipping by 2035; OECD: Paris, France, 2018.

[9] Ammonia Energy Association, Ammonia for power: a literature review – By Trevor Brown Oct.04,2018

[10] International Association of Classification Societies – URH 1

[11] ABS - Ammonia as Marine Fuel White paper – October 2020

[12] Bureau Veritas – NR 671 RO1

[13] Det Norske Veritas, White paper 2020

[14] Indian Register of Shipping Guidelines on Ammonia fueled vessels – December 2022

[15] LRS - Rules and Regulations for the Classification of Ships using Gases or other Low-flashpoint Fuels, July 2022 - Chapter 1 Appendices

[16] NK – Part C – Guidelines for the safety of Ships using ammonia as fuel.

[17] https://www.classnk.or.jp/hp/pdf/research/rd/2022/05_e07.pdf

[18] Article- Ammonia for power: A literature review, Trevor Brown Oct4, 2018, Ammonia Energy Association.

[19] MAN ES technical paper, Engineering the future two-stroke green-ammonia engine, November 2019

[20] Wartsila - Article-swz-maritime-magazine-types-of fuel- March 2020., Safe and effective operation of engines with Ammonia and Methanol 19th International Maritime Conference 2023 Tallinn. Fredrik Lindfors, Wärtsilä Marine Power Supply, R&D and Engineering, 4th of October 2023

[21] WinGD - TIN035 Dual-Fuel-Ammonia-Engine-Development Dec. 2023 Technical information note 035

[22] Linde Engineering Green seminar 2021

[23] Yara International Ammonia You tube video

[24] Stargate White paper

[25] Ammonia : Zero carbon fertiliser, fuel, and energy store policy briefing – The Royal Society].

[26] IMO Resolution MSC5(48) IGC code 16.9.2 https://www.imo.org/en/OurWork/Safety/Pages/IGC-Code.

[27] Class NK : https://www.classnk.or.jp/hp/pdf/research/rd/2022/05_e07.pdf

[28] MARPOL : http://www.marpoltraining.com/Annex II- Regulations for the Control of Pollution by Noxious Liquid Substances in Bulk – Chapter 1- Reg. 5,

[29] Maritime Technologies forum - Preliminary discussion report on the use of ammonia as fuel for ships. www.maritimetechnologiesforum.com/documents/ammonia-report.pdf

[30] Ammonfuel article – An industrial view of ammonia as a marine fuel 59 / 61 August 2020

[31] https://shippingwatch.com/regulation/article15928061.ece

[32] Shipping watch article - Wartsila test-runs 90 percent ammonia-fueled engine

[33] MAN-B&W -

[34] The impossible love of fossil fuel companies for carbon taxes – Elsevier Ecological Economics, Alain Naef 2 Nov. 23, 27 – Putting a price on pollution- Ian Perry De. 2019], IMF article

[35] SCR - MAN Energy solutions- https://www.man-es.com/marine/solutions/exhaust_gas_after_treatment_systems?utm_medium.

[36] MAN-B&W: Two stroke engine operating on ammonia – Future in the making – White paper

[37] Progress on safety guidelines for hydrogen- and ammonia-fuelled ships https://www.imo.org/en/MediaCentre/Pages/WhatsNew-1968.aspx - 05 October 2023

[38] https://www.seatrade-maritime.com/sustainability-green-technology/alternative-fuels-training-needed-800000-seafarers-mid-2030s Marcus Hand Nov. 09, 2022 Article

[39] Department of agriculture. (https://www.mda.state.mn.us/physical-chemical-properties-anhydrous-ammonia)

[40] Decarbonization in ammonia production, new technological methods in industrial scale ammonia production and critical evaluations – Heliyon , www.cell.com/heliyon - Abdullah E Yuzbasioglu et al

[41] Muhammad Aziz , Agung Tri Wijayanta , Asep Bayu Dani Nandiyanto. Ammonia as Effective Hydrogen Storage: A Review on Production, Storage and Utilization. Energies – 12 June 2020

[42] MAN – B&W https://www.man-es.com/docs/default-source/marine/tools/man-b-w-two-stroke-engine-operating-on-ammonia.pdf

[43] Article - https://netl.doe.gov/sites/default/files/netl-file/ACT_0324_Wilche.pdf

[44] Wartsila - https://www.wartsila.com/marine/decarbonisation/partnerships-and-project-involvement/demo2000

[45] The Impact of Ammonia Fuel on Marine Engine Lubrication: An Artificial Lubricant Ageing Approach – et al

[46] https://www.researchgate.net/publication/369888542_The_Impact_of_Ammonia_Fuel_on_Marine_Engine_Lubrication_An_Artificial_Lubricant_Ageing_Approach

[47] ABS Sustainability Whitepaper Ammonia as a Marine Fuel October 2020

[48] https://safety4sea.com/wp-content/uploads/2021/01/Ammonia_as_Marine_Fuel_Whitepaper_20188.pdf

[49] Preliminary discussion report on the use of Ammonia as fuel for ships

[50] https://www.maritimetechnologiesforum.com/documents/ammonia-report.pdf

[51] National Library of Medicine

[52] https://www.ncbi.nlm.nih.gov/books/NBK207883/

[53] MAN Energy Solutions – Ship operation using LPG and Ammonia as fuel on MAN B&W dual fuel ME-LGIP engines- Presentation by Rene Sejer Laursen – 30 Oct. 2018

[54] The National Institute for occupational safety and health (NIOSH)

[55] https://www.cdc.gov/niosh/npg/npgd0028.html

[56] MAN ES technical paper, Engineering the future two-stroke green-ammonia engine, November 2019

[57] https://www.researchgate.net/publication/369888542_The_Impact_of_Ammonia_Fuel_on_Marine_Engine_Lubrication_An_Artificial_Lubricant_Ageing_Approach ResearchGate - Adam Agcos et al

[58] Lubricant performance and reliability of ammonia fueled IC engines

[59] https://www.sae.org/publications/technical-papers/content/2023-32-0104/

[60] - Nicolas Obrecht, Bruno Griffaton, et al

[61] Online article Pollution Solutions. Online Feb. 05 – 2014 Author: Chris Sergeant on behalf of Cancer Research UK Cambridge Institute

[62] IMO rules.com/IGC_CH14.html

[63] United States National Canter for Biotechnology Information

[64] MAN ES technical paper – Engineering the future two stroke green-ammonia engine, November 2019

[65] National Institute of Standard and Technology Ammonia. Available online: https://webbook.nist.gov/cgi/

[66] https://ammoniaenergy.org/articles/ammonia-for-fuel-cells-a-literature-review/

[67] Ammonia for Fuel Cells: a literature review

[68] By Trevor Brown on October 04, 2018

[69] Lan, R.; Tao, S. Ammonia as a Suitable Fuel for Fuel Cells.

[70] Front Energy Res. 2014, 2.

[71] MAN ES technical paper – Engineering the future two stroke green-ammonia engine, November 2019

[72] Ammonia Energy Association article by Julion Atchison 6th Feb. 2024

[73] Alfa Laval. Press release. The Alfa Laval FCM LPG Booster System Excels with the New LPG-Fuelled Engine from MAN Energy Solutions; Alfa Laval: Lund, Sweden, 2019.

[74] Offshore Vessel to Run on Ammonia-Powered Fuel Cell. Available online: https://www.maritime-executive.com/article/offshore-vessel-to-run-on-ammonia-powered-fuel-cell

[75] The Crown (Department for Transport). Clean Maritime Plan; The Crown: London, UK, 2019.

[76] Hunter, H.M.A.; Makepeace, J.W.; Wood, T.J.; Mylius, O.S.; Kibble, M.G.; Nutter, J.B.; Jones, M.O.; David, Demonstrating Hydrogen Production from Ammonia Using Lithium Imide—Powering a Small Proton Exchange Membrane Fuel Cell. J. Power Sources 2016, 329, 138–147.

[77] IMO – MEPC 77/6/1 – 20 August 202.

[78] Lloyd’s Register (LR) & University Maritime Advisory Services (UMAS). Zero-Emission Vessels 2030—How Do We Get There; LR: London, UK; UMAS: London, UK, 2017.

[79] Det Norske Veritas , White paper 2020

[80] Qiuwen Wang, Hu Zhang, Jiabei Huang and Pengfei Zhang. The use of alternative fuels for maritime decarbonization: Special marine environmental risks and solutions from an international law perspective.

[81] Acute Exposure Guideline Levels for Selected Airborne Chemicals: Volume 6. http://www.nap.edu/catalog/12018.html